# THE INFRARED SPECTRUM AND BARRIERS HINDERING INTERNAL ROTATION IN $H_{2}S_{2}, CF_{3}SH$ AND $CF_{3}SD$

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 dc.creator Redington, R. L. en_US dc.date.accessioned 2006-06-15T16:16:03Z dc.date.available 2006-06-15T16:16:03Z dc.date.issued 1962 en_US dc.identifier 1962-G-1 en_US dc.identifier.uri http://hdl.handle.net/1811/14411 dc.description Author Institution: Mellon Institute en_US dc.description.abstract The infrared spectrum of gaseous $H_{2}S_{2}, CF_{3}SH$ and $CF_{3}SD$ has been observed down to $100 cm^{-1}$. From the observed torsion frequencies, the barriers hindering internal rotation are suggested as about $2400 cm^{-1}$ for $H_{2}S_{2}$, and $425 cm^{-1}$ for $CF_{3}SH$. The potential function implies that the dihedral angle of $H_{2}S_{2}$ is close to $90^{\circ}$. The fundamental frequency assignments of $CF_{3}SH$ are discussed. en_US dc.format.extent 65747 bytes dc.format.mimetype image/jpeg dc.language.iso English en_US dc.publisher Ohio State University en_US dc.title THE INFRARED SPECTRUM AND BARRIERS HINDERING INTERNAL ROTATION IN $H_{2}S_{2}, CF_{3}SH$ AND $CF_{3}SD$ en_US dc.type article en_US