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THE $S_{1} \leftarrow S_{0}$ FLUORESCENCE EXCITATION SPECTRA OF ANISOLE AND STYRENE UING HIGH RESOLUTION TECHNIQUES

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13949

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dc.creator Ribblett, Jason W. en_US
dc.creator Pratt, D. W. en_US
dc.date.accessioned 2006-06-15T15:43:06Z
dc.date.available 2006-06-15T15:43:06Z
dc.date.issued 1997 en_US
dc.identifier 1997-RE-10 en_US
dc.identifier.uri http://hdl.handle.net/1811/13949
dc.description Author Institution: Department of Chemistry, University of Pittsburgh en_US
dc.description.abstract Anisole (methoxybenzene) and styrene (vinylbenzene) are similar chemical species. However, their electronic strucures are very different. In this report, we describe the rotationally resolved fluorescence excitation spectra of the $S_{1} \leftarrow S_{u}$ origin bands of anisole and styrene. Both spectra are similar in overall appearance. However, a detailed analysis of the two spectra shows that the $S_{1} \leftarrow S_{0}$ optical transition moments have quite different orientations in the respective molecular frames. The results will be interpreted in the framework of a state-mixing model for the $S_{1}$ states of the two molecules. en_US
dc.format.extent 71079 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title THE $S_{1} \leftarrow S_{0}$ FLUORESCENCE EXCITATION SPECTRA OF ANISOLE AND STYRENE UING HIGH RESOLUTION TECHNIQUES en_US
dc.type article en_US