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INFRARED SPECTRA OF MOLECULAR IONS FORMED FROM $SF_{4}$ AND $SF_{6}$ AND TRAPPED IN A NEON MATRIX

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13936

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Title: INFRARED SPECTRA OF MOLECULAR IONS FORMED FROM $SF_{4}$ AND $SF_{6}$ AND TRAPPED IN A NEON MATRIX
Creators: Lugez, Catherine L.; Jacox, Marilyn E.; King, Rollin A.; Schaefer, H. F., III
Issue Date: 1997
Abstract: When $SF_{4}$ or $SF_{6}$ is subjected to Penning ionization and photoionization by excited neon atom and their resonance radiation (16.6-16.8 eV) and the products are rapidly frozen in an excess of solid neon, the resulting solid deposit shows prominent infrared absorptions which can be assigned to cation and anion products. Among the species identified through their infrared absorptions are $SF_{3}^{+}, SF_{5}^{+}, SF_{5}^{+}$, and $F_{2}SO^{+}$. The assignments are aided by consideration of the spectra of related system and by the results of ab initio calculations.
URI: http://hdl.handle.net/1811/13936
Other Identifiers: 1997-RD-07
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