# INFRARED SPECTRA OF MOLECULAR IONS FORMED FROM $SF_{4}$ AND $SF_{6}$ AND TRAPPED IN A NEON MATRIX

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13936

Files Size Format View
1997-RD-07.jpg 76.62Kb JPEG image

 Title: INFRARED SPECTRA OF MOLECULAR IONS FORMED FROM $SF_{4}$ AND $SF_{6}$ AND TRAPPED IN A NEON MATRIX Creators: Lugez, Catherine L.; Jacox, Marilyn E.; King, Rollin A.; Schaefer, H. F., III Issue Date: 1997 Publisher: Ohio State University Abstract: When $SF_{4}$ or $SF_{6}$ is subjected to Penning ionization and photoionization by excited neon atom and their resonance radiation (16.6-16.8 eV) and the products are rapidly frozen in an excess of solid neon, the resulting solid deposit shows prominent infrared absorptions which can be assigned to cation and anion products. Among the species identified through their infrared absorptions are $SF_{3}^{+}, SF_{5}^{+}, SF_{5}^{+}$, and $F_{2}SO^{+}$. The assignments are aided by consideration of the spectra of related system and by the results of ab initio calculations. Description: Author Institution: Optical Technology Division, National Institute of Standard and Technology; Center for Computational Chemistry, University of Georgia URI: http://hdl.handle.net/1811/13936 Other Identifiers: 1997-RD-07