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FT MICROWAVE SPECTRUM OF SULFUR CHLORIDE FLUORIDE, CISF

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13888

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dc.creator Preusser, Jurgen en_US
dc.creator Gerry, Michael C. L. en_US
dc.date.accessioned 2006-06-15T15:41:30Z
dc.date.available 2006-06-15T15:41:30Z
dc.date.issued 1997 en_US
dc.identifier 1997-MI-10 en_US
dc.identifier.uri http://hdl.handle.net/1811/13888
dc.description Author Institution: Department of Chemistry, The University of British Columbia en_US
dc.description.abstract The microwave spectrum of sulfur chloride, CISF, has been measured for the first time, using a pulsed-jet cavity Fourier-transform microwave spectrometer. The samples were prepared from mixtures of $SCL_{2}/SF_{6}OTCl_{2}/SF_{6}$ in Ne carrier gas, using an electric discharge nozzle. Spectra of three isotopomers $(^{35} CI^{32}S^{19}F,\ \ ^{37}CI^{32}S^{19}F$, and $^{35}CI^{34}S^{19}F)$ have been observed in natural abundance, and have been analysed to produce rotation constants, centrifugal distortion constants, and hyperfine parameters of CI and F. The molecular geometry has been derived. The harmonic force field has been refined, and used as part of the structure determination. The CI quadrupole coupling constants and F spin-rotation constants have given information on the electronic structure. In particular, some rather unusual, negative, F spin-rotational constants will be discussed in terms of a potential electronic spectrum. en_US
dc.format.extent 93234 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title FT MICROWAVE SPECTRUM OF SULFUR CHLORIDE FLUORIDE, CISF en_US
dc.type article en_US