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$S_{1}-S_{0}$ TRANSITION MOMENT ORIENTATIONS IN AROMATIC $ETHERS^{*}$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13613

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dc.creator Ribblett, Jason W. en_US
dc.creator Pratt, D. W. en_US
dc.date.accessioned 2006-06-15T15:33:53Z
dc.date.available 2006-06-15T15:33:53Z
dc.date.issued 1996 en_US
dc.identifier 1996-TB-06 en_US
dc.identifier.uri http://hdl.handle.net/1811/13613
dc.description $^{*}$ Work supported by NSF en_US
dc.description Author Institution: Department of Chemistry, University of Pittsburg, Pittsburg en_US
dc.description.abstract Rotationally resolved fluorescence excitation spectra of the four origin bands that appear in the $S_{1}-S_{0}$ electronic transition of methyl -3-methoxybenzoate have been obtained and analyzed. The four origins have been assigned to conformers associated with cis and trans configurations of the $OCH_{3}$ substituent and cis and trans configurations of the ester substituent, based on their inertial parameters. Further analysis makes possible llie determination of the absolute orientation of the transition moment in the molecular frame of each of the four conformers and its dependence upon both the inertial and electronic properties of the substituents. en_US
dc.format.extent 61337 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title $S_{1}-S_{0}$ TRANSITION MOMENT ORIENTATIONS IN AROMATIC $ETHERS^{*}$ en_US
dc.type article en_US