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INTERACTION BETWEEN VIBRATIONS AND INTERNAL ROTATION IN $S_{1}$ M-FLUOROTOLUENE AS SEEN IN THE $S_{1}-S_{0}$ SPECTROSCOPY

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13609

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dc.creator Ju, Quan en_US
dc.creator Parmenter, C. S. en_US
dc.date.accessioned 2006-06-15T15:33:48Z
dc.date.available 2006-06-15T15:33:48Z
dc.date.issued 1996 en_US
dc.identifier 1996-TB-02 en_US
dc.identifier.uri http://hdl.handle.net/1811/13609
dc.description Author Institution: Department of Chemistry, Indiana University en_US
dc.description.abstract In support of IVR studies in m-fluorotoluene, a detailed picture is being constructed of the vibrational and internal rotation level structure for the lower $430 cm^{-1}$ of the S1 slate. Particular emphasis is given to Fermi resonances involving interactions between internal rotation and vibration. The information is derived from cold jet $S_{1}-S_{0}$ spectroscopy with abundant use of dispersed single vibronic level fluorescene (SVLF), Seventy-five levels involving internal rotation as well as eight modes occuring as fundamentals, overtones and combinations occour with known zero order identities in the energy region. Of these, twenty-six have been pumped for examinnation by SVLF spectroscopy. Clear evidence for numerous level interactions appears in the spectra. The details are now being worked out. en_US
dc.format.extent 76860 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title INTERACTION BETWEEN VIBRATIONS AND INTERNAL ROTATION IN $S_{1}$ M-FLUOROTOLUENE AS SEEN IN THE $S_{1}-S_{0}$ SPECTROSCOPY en_US
dc.type article en_US