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PHOTOCHEMISTRY AND SPECTROSCOPY OF MATRIX ISOLATED $C_{3}\cdot H_{2}O$ COMPLEX

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13297

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dc.creator Szczepanski, J. en_US
dc.creator Ekern, S. en_US
dc.creator Vala, Martin en_US
dc.date.accessioned 2006-06-15T15:25:49Z
dc.date.available 2006-06-15T15:25:49Z
dc.date.issued 1994 en_US
dc.identifier 1994-TG-07 en_US
dc.identifier.uri http://hdl.handle.net/1811/13297
dc.description Author Institution: Department of Chemistry, University of Florida en_US
dc.description.abstract Fourier transform infrared absorption measurements of Nd/YAG-laser-ablated isotopic mixtures of $^{13}C$ and $^{12}C$ isolated with water in argon matrices have revealed the existence of a complex of $^{12/13}C_{3}$ with water. The structure of the complex, deduced from a normal coordinate analysis of the vibrational spectrum; and from a HF/6-31$G^{*}$ ab initio calculations, will be discussed. Photolysis (405 nm) of the matrix sample leads the disappearance of the complex bands and the formation of two conformers of 3-hydroxypropadienylidene. The predicted structure and vibrational spectrum of these intermediates, calculated via {ab initio} theory, will be compared to experimental results. en_US
dc.format.extent 71516 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title PHOTOCHEMISTRY AND SPECTROSCOPY OF MATRIX ISOLATED $C_{3}\cdot H_{2}O$ COMPLEX en_US
dc.type article en_US