OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

The Knowledge Bank is scheduled for regular maintenance on Sunday, April 20th, 8:00 am to 12:00 pm EDT. During this time users will not be able to register, login, or submit content.

PHOTOCHEMISTRY AND SPECTROSCOPY OF MATRIX ISOLATED $C_{3}\cdot H_{2}O$ COMPLEX

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13297

Show full item record

Files Size Format View
1994-TG-07.jpg 69.83Kb JPEG image Thumbnail of PHOTOCHEMISTRY AND SPECTROSCOPY OF MATRIX ISOLATED $C_{3}\cdot H_{2}O$ COMPLEX

Title: PHOTOCHEMISTRY AND SPECTROSCOPY OF MATRIX ISOLATED $C_{3}\cdot H_{2}O$ COMPLEX
Creators: Szczepanski, J.; Ekern, S.; Vala, Martin
Issue Date: 1994
Abstract: Fourier transform infrared absorption measurements of Nd/YAG-laser-ablated isotopic mixtures of $^{13}C$ and $^{12}C$ isolated with water in argon matrices have revealed the existence of a complex of $^{12/13}C_{3}$ with water. The structure of the complex, deduced from a normal coordinate analysis of the vibrational spectrum; and from a HF/6-31$G^{*}$ ab initio calculations, will be discussed. Photolysis (405 nm) of the matrix sample leads the disappearance of the complex bands and the formation of two conformers of 3-hydroxypropadienylidene. The predicted structure and vibrational spectrum of these intermediates, calculated via {ab initio} theory, will be compared to experimental results.
URI: http://hdl.handle.net/1811/13297
Other Identifiers: 1994-TG-07
Bookmark and Share