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HIGH RESOLUTION SPECTROSCOPY OF THE $a^{3}\Pi_{r}-X^{1}\Sigma'$ TRANSITION OF BCl

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13225

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dc.creator Mahoney, K. I. en_US
dc.creator Brett, R. J. en_US
dc.creator Mathews, C. W. en_US
dc.date.accessioned 2006-06-15T15:24:06Z
dc.date.available 2006-06-15T15:24:06Z
dc.date.issued 1994 en_US
dc.identifier 1994-TA-14 en_US
dc.identifier.uri http://hdl.handle.net/1811/13225
dc.description 1. H. Bredohl, I. Dubois, and F. Melen, J. Mol. Spectrosc. 121, 135-138 (1987). 2. A.G. Maki, F. J. Lovas, and R.D. Suenram, J. Mol. Spectrosc. 91, 424-429 (1982). en_US
dc.description Author Institution: Laser Spectroscopy Facility, Department of Chemistry, The Ohio State University en_US
dc.description.abstract The $a^{3}\Pi_{r}-X^{1}\Sigma^{-}$ transition of BCl has been recorded at $0.02 cm^{-1}$ resolution using a Bruker IFS 120 HR Fourier Transform spectrometer The $\Delta\nu=0$ bands up to $\nu^{\prime}=4$ and $\Delta\nu=-1$ bands up to $\nu=1$ were observed, and 693 fines were assigned. The increased dynamic range of intensities for the fourier transform spectrometer over photographic recordings has allowed for the first rotational analysis of all four isotopomers of BCI. The most intense band, the 0-0 near $20 200 cm^{-1}$, has been analyzed for $^{11}B^{35}Cl, ^{11}B^{32}Cl ^{10}B^{35}Cl,$ and $^{10}B^{32}Cl4$. The standar deviation of these fittings was about $0.015 cm^{-1}$, and the constants are in agreement with previous reports $^{1,2}$ The other bands are currently be analyzed. en_US
dc.format.extent 94332 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title HIGH RESOLUTION SPECTROSCOPY OF THE $a^{3}\Pi_{r}-X^{1}\Sigma'$ TRANSITION OF BCl en_US
dc.type article en_US