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HIGH RESOLUTION FTIR SPECTROSCOPY OF THE $\nu_{2}$ BAND OF SULFINE, $H_{2}CSO$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13204

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dc.creator Joo, D.- L. en_US
dc.creator Clouthier, Dennis J. en_US
dc.creator Lai, V. en_US
dc.creator Ma, E. en_US
dc.creator Chan, C. P. en_US
dc.creator Merer, A. J. en_US
dc.date.accessioned 2006-06-15T15:23:36Z
dc.date.available 2006-06-15T15:23:36Z
dc.date.issued 1994 en_US
dc.identifier 1994-RH-09 en_US
dc.identifier.uri http://hdl.handle.net/1811/13204
dc.description Author Institution: Department of Chemistry, University of Kentucky; Department of Chemistry, The University of British Columbia en_US
dc.description.abstract The rotational analysis of the $\nu_{9}$ ($CH_{2}$ wagging) fundamental at $762 cm^{-1}$ of sulfine will be presented. Spectra of this transient molecule were obtained by flowing the products of the $700^{\circ} C$ pyrolysis of dimethyl sulfoxide vapor through a multipass cell mounted on a Bomem DA3.002 spectrometer. The strong {C}-type fundamental has unperturbed rotational structure at low J and $K_{a}$, but interacts with the $2\nu_{2}$ level at higher rotational energies, through A- and B-axis Coriolis coupling. The general energy level scheme for the interacting levels will be discussed. en_US
dc.format.extent 77412 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title HIGH RESOLUTION FTIR SPECTROSCOPY OF THE $\nu_{2}$ BAND OF SULFINE, $H_{2}CSO$ en_US
dc.type article en_US