# Vibrational Analysis of the $\tilde{A}\leftarrow \tilde{X}$ transition of $Rg\bullet$SH Complexes (Rg = Ne, Ar and Kr)

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13149

Files Size Format View
1994-RD-10.jpg 90.15Kb JPEG image

 Title: Vibrational Analysis of the $\tilde{A}\leftarrow \tilde{X}$ transition of $Rg\bullet$SH Complexes (Rg = Ne, Ar and Kr) Creators: Yang, Min-Chieh; Salzberg, Aldo P.; Carter, Christopher C.; Miller, Terry A. Issue Date: 1994 Publisher: Ohio State University Abstract: The LIF spectra of Rg $\cdot$ SH complexes have been observed. Vibrational analysis of these spectra indicates that in Ne $\ast$ SH, most of observed bands are transitions to the internal rotational levels of the $\bar A$ state. In $Ar\ast$ SH and $Kr\ast$ SH, we observed both pure van der Waals stretch bands and bend-stretch combination bands. Based on the isotopic shift between $Kr^{88}\ast$ SH and $Kr^{84}\ast$ SH, we are able to determine the absolute vibrational assignment of most observed $Kr\ast$ SH bands. The details of analysis will be presented. Description: Author Institution: Laser Spectroscoy Facility, Department of Chemistry, The Ohio State University URI: http://hdl.handle.net/1811/13149 Other Identifiers: 1994-RD-10