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Vibrational Analysis of the $\tilde{A}\leftarrow \tilde{X}$ transition of $Rg\bullet $SH Complexes (Rg = Ne, Ar and Kr)

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/13149

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Title: Vibrational Analysis of the $\tilde{A}\leftarrow \tilde{X}$ transition of $Rg\bullet $SH Complexes (Rg = Ne, Ar and Kr)
Creators: Yang, Min-Chieh; Salzberg, Aldo P.; Carter, Christopher C.; Miller, Terry A.
Issue Date: 1994
Abstract: The LIF spectra of Rg $\cdot$ SH complexes have been observed. Vibrational analysis of these spectra indicates that in Ne $\ast$ SH, most of observed bands are transitions to the internal rotational levels of the $\bar A$ state. In $Ar\ast$ SH and $Kr\ast$ SH, we observed both pure van der Waals stretch bands and bend-stretch combination bands. Based on the isotopic shift between $Kr^{88}\ast$ SH and $Kr^{84}\ast$ SH, we are able to determine the absolute vibrational assignment of most observed $Kr\ast$ SH bands. The details of analysis will be presented.
URI: http://hdl.handle.net/1811/13149
Other Identifiers: 1994-RD-10
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