The $V_{3} = 1$ vibrational level In $C_{2}H_{2}$

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dc.creator Auwera, J. Vander en_US
dc.creator Hurtmans, D. en_US
dc.creator Carleer, M. en_US
dc.creator Herman, M. en_US 2006-06-15T15:14:40Z 2006-06-15T15:14:40Z 1992 en_US
dc.identifier 1992-TA-04 en_US
dc.description Author Institution: Laboratoire de Chimie Physique, Mol\'{e}culaire Universit\'{e} libre de Bruxelles en_US
dc.description.abstract We have used a Bruker Fourier transform interferometer IFS120HR to record spectra at high resolution of various bands reaching the entire set of levels interacting with $V_{3}$ - 1 through Fermi or l-type couplings. Their rotational structure was assigned and the various interactions were departurbed using a full matrix approach. Absolute line intensity measurements were performed for the rotational lines in the two bands observed around 3$\mu$m and processed with a home made computer program taking into account the various Doppler, pressure and instrumental line shapes. The corresponding induced dipole moments were derived through both an effective treatment, Involving Herman-Wallis factors, and the full matrix treatment, including the various rovibrational couplings taken into account for the energy deporturbation. The results and their accuracy will be discussed. en_US
dc.format.extent 87318 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.publisher Ohio State University en_US
dc.title The $V_{3} = 1$ vibrational level In $C_{2}H_{2}$ en_US
dc.type article en_US