ABSOLUTE ABSORPTION OF OZONE IN THE MID-INFRARED

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Title: ABSOLUTE ABSORPTION OF OZONE IN THE MID-INFRARED
Creators: Pickett, H. M.; Peterson, D. B.; Margolis, J. S.
Issue Date: 1992
Publisher: Ohio State University
Abstract: A number of spectroscopic investigators have measured ozone absolute intensities in different spectral regions. The mid-infrared frequencies have been studied by two $techniques ^{1,2}$. We report here the results of a distinctly different determination of the absorption cross section using a Bruker HR 120 Fourier transform spectrometer in the mid-infrared region. In this study, the infrared and ultraviolet, absorption of ozone were measured simultaneously using selected infrared lines of the $\nu_{3}$ band and the ultraviolet 253.7 nm Hg line. The accuracy of our absolute infrared intensity measurements are comparable to the 1 \% spread in the ultraviolet absorption measurements at 253.7 $nm^{3}$.
Description: $^{1}$ C. Secroun, A. Barbe, P. Jouve, P. Arcas, and E. Arie, J. Mol Spectrosc. {\bf 85} , 8--15 (1981). $^{2}$ J. M. Hoell, JR., C. N. Harward, C. H. Blair, and B. S. Williams, Opt. Eng. {\bf 21} , 548--552 (1982). $^{3}$ L. T. Molina and M. J. Molina, J. Geophys. Res. {\bf 91} , 14501--14508 (1986).
Author Institution: Jet Propulsion Laboratory, California Institute of Technology
URI: http://hdl.handle.net/1811/12803
Other Identifiers: 1992-RF-12
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