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The High Resolution Emission Spectra of Gaseous Aluminum Monohalides

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/12676

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dc.creator Hedderich, Hartmut G. en_US
dc.creator McBrien, Mike en_US
dc.creator Bernath, P. F. en_US
dc.date.accessioned 2006-06-15T15:10:36Z
dc.date.available 2006-06-15T15:10:36Z
dc.date.issued 1992 en_US
dc.identifier 1992-ME-04 en_US
dc.identifier.uri http://hdl.handle.net/1811/12676
dc.description Author Institution: Department of Chemistry, University of Waterloo en_US
dc.description.abstract At high temperatures aluminum monohalides are easily produced in the gas phase by heating $AlX_{3}$ ($X=F$, $Cl$, $Br$, $I$) with Al. The high resolution infrared emission spectrum of AIF was measured with the McMath Fourier transform interferometer at Kitt Peak. The ro-vibrational emission spectrum of AICI was measured with the Bruker IFS 120 HR Fourier transform spectrometer at the University of Waterloo. About 500 lines of AIF and more than 2000 lines of AlCl were observed. These ro-vibrational transitions and pure rotational transitions form the literature were fit to a set of Dunham coefficients $Y_{ij}$. In the case of AlCl a set of mass-reduced Dunham coefficients $U_{ij}$ were also determined. en_US
dc.format.extent 81414 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title The High Resolution Emission Spectra of Gaseous Aluminum Monohalides en_US
dc.type article en_US