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THE 10$\mu$m SPECTRUM OF ACETALDEHYDE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/12614

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dc.creator Fraser, G. T. en_US
dc.creator Pate, Brooks H. en_US
dc.creator Tretyakov, M. Yu. en_US
dc.date.accessioned 2006-06-15T15:09:06Z
dc.date.available 2006-06-15T15:09:06Z
dc.date.issued 1992 en_US
dc.identifier 1992-FA-03 en_US
dc.identifier.uri http://hdl.handle.net/1811/12614
dc.description Author Institution: Molecular Physics Division, National Institute of Standards and Technology; Molecular Spectroscopy Laboratory, Applied Physics Institute en_US
dc.description.abstract The 10$\mu$m in-plane methyl rock normal mode of acetaldehyde has been measured using a $CO_{2}$ (or $N_{2}O$) laser side band system and the EROS spectrometer. Using both $CO_{2}$ and $N_{2}O$ laser lines we have approximately 80\% coverage of the spectrum from $912-9 cm^{-1}$. The beam is formed in a weak He expansion which results in population in both $v=0$ and $v=1$ of the torsion. This study is aimed at understanding the vibrational interactions in a spectroscopically well-characterized molecule containing an internal methyl rotor. The spectrum is found to be quite dense and extensively perturbed. The possible interactions with the bath states and the coupling strengths will be discussed. en_US
dc.format.extent 83378 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title THE 10$\mu$m SPECTRUM OF ACETALDEHYDE en_US
dc.type article en_US