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INFRARED FLASH KINETIC SPECTROSCOPY OF THE KETENYL RADICAL

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/12346

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dc.creator Unfried, Kenneth G. en_US
dc.creator Glass, Graham P. en_US
dc.creator Curl, R. F., Jr. en_US
dc.date.accessioned 2006-06-15T15:02:31Z
dc.date.available 2006-06-15T15:02:31Z
dc.date.issued 1991 en_US
dc.identifier 1991-FB-5 en_US
dc.identifier.uri http://hdl.handle.net/1811/12346
dc.description Author Institution: Chemistry Department, Rice University en_US
dc.description.abstract The high resolution infrared spectrum of the heavy atom antisymmetric stretch vibration of the ketenyl radical (HCCO) has been observed by means of infrared kinetic spectroscopy using 193 nm photolysis of ketene followed by diode laser probing of the the transient absorption. Individual ro-vibrational transitions have been identified near the band origin located at approximately $ 2023 cm^{-1}$. This spectroscopic technique will be presented, along with the observed spectra, assignments and parameters obtained from a least squares fit of the data. en_US
dc.format.extent 71690 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title INFRARED FLASH KINETIC SPECTROSCOPY OF THE KETENYL RADICAL en_US
dc.type article en_US