VIBRATIONAL CIRCULAR DICHROISM OF (R)-(+)-3-METHYLCYCLOPENTANONE

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Title: VIBRATIONAL CIRCULAR DICHROISM OF (R)-(+)-3-METHYLCYCLOPENTANONE
Creators: Laux, Leo J.; Hansen, John C.; Moscowitz, Albert
Issue Date: 1985
Publisher: Ohio State University
Abstract: The vibrational circular dichroism (VCD) spectra of (R)-(+)-3-methylcyclopentanone and its $2,2,5,5-d_{4}$ derivative in $CCl_{4}$ solution have been measured in the C-H and C-D stretching regions. The deuterated species shows a large $(|R| \sim 70 \times 10^{-45} esu^{2} cm^{2})$ bisignate VCD spectrum in the C-D stretching region. Attempts to account for these data by coupling among only four erstwhile degenerate C-D stretching modes fails. The data are better accounted for by more complex descriptions of the nuclear motions and attendant electronic charge flows that involve additional moieties, e.g. the carbonyl group.
Description: Author Institution: Department of Chemistry, University of Minnesota; Lockheed Palo Alto Research Laboratories, University of Minnesota
URI: http://hdl.handle.net/1811/12272
Other Identifiers: 1985-WE-12
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