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EXPERIMENTAL DETERMINATION TO LARGE INTERNUCLEAR SEPARATION OF THE '$\Sigma^{+}$ STATE ELECTRIC DIPOLE MOMENT FUNCTION OF CO

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/11943

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Title: EXPERIMENTAL DETERMINATION TO LARGE INTERNUCLEAR SEPARATION OF THE '$\Sigma^{+}$ STATE ELECTRIC DIPOLE MOMENT FUNCTION OF CO
Creators: Chackerian, C., Jr.; Farrenq, R.; Guelachvili, G.; Rossetti, C.; Urban, W.
Issue Date: 1983
Abstract: We have experimentally determined the EDMF of CO’s ground electronic state to about the classical turning points of the V=40th level. The $Pade’$ approximant representation of the EDMF is determined via a non-linear least-squares fit which combines numerically obtained vibrational wavefunctions and experimentally determined vibrational band intensities for which $\Delta v=1,2,3$ and 40 for both emission spectra by considering pairs of vibrational transitions from common upper vibrational states and assuming a well defined rotational temperature. These results should be useful in the interpretation of solar infrared spectra.
URI: http://hdl.handle.net/1811/11943
Other Identifiers: 1983-TA-04
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