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THE HIGH RESOLUTION SPECTROSCOPY OF CYCLOPROPANE $\nu_{9} + \nu_{10}$ COMBINATION BAND PERTURBED BY FERMI AND CORIOLIS RESONANCES

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/11774

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Title: THE HIGH RESOLUTION SPECTROSCOPY OF CYCLOPROPANE $\nu_{9} + \nu_{10}$ COMBINATION BAND PERTURBED BY FERMI AND CORIOLIS RESONANCES
Creators: Qingshi, Zhu; Zhiye, Shen; Huihua, Shen; Huifang, Liu; Zhang, Baoshu; Runlan, Huang; Cunhao, Zhang
Issue Date: 1983
Abstract: The combination band $\nu_{9} + \nu_{10}$ of cyclopropane was found, the band center is $2464.52 cm^{-1}$, it’s FTIR and diode laser spectroscopy studies are reported here. The transitions are assigned and least square fitted to estimate the molecular constants. The anomalies observed in the rotational structure of $\nu_{9} + \nu_{10}$ band are attributed to the Fermi and Coriolis interactions between $\nu_{9} + \nu_{10}$ and $\nu_{2} + \nu_{10}, \nu_{5} + \nu_{9}$, and the $l$-type resonances. The J-structure of Qk(J)’s in the diode laser Spectrum display very clearly a variation of $(B^{\prime}-B_{D})$ as a function of K which provides a good example for the study on this type of effect of Fermi resonance.
URI: http://hdl.handle.net/1811/11774
Other Identifiers: 1983-FA-11
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