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DIODE LASER SPECTROSCOPY OF THE FCO RADICAL

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/11581

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dc.creator Nagai, Keiichi en_US
dc.creator Yamada, Chikashi en_US
dc.creator Endo, Yasuki en_US
dc.creator Hirota, Eizi en_US
dc.date.accessioned 2006-06-15T14:40:04Z
dc.date.available 2006-06-15T14:40:04Z
dc.date.issued 1981 en_US
dc.identifier 1981-RA-5 en_US
dc.identifier.uri http://hdl.handle.net/1811/11581
dc.description Author Institution: en_US
dc.description.abstract The FCO radical was detected in the gas phase by the diode laser spectrometer. Bands corresponding to the C-O stretching $(\nu_{1}, 5.4\mu m)$ and the C-F stretching $(\nu_{2}, 10\mu m)$ were observed. To confirm that the observed spectra are due to FCO, we also observed $F^{13}CO$ spectrum in the $\nu_{1}$ band. The FCO radical was generated by an A.C. discharge in the mixtures of\\ (1) $C_{2}F_{4}$, (100mTorr) $+ O_{2}$ (100mTorr) $+$ He\\ (2) $SF_{6}$ (B0mTorr) $+$ CO (150mTorr) $+$ He\\ (3) $C_{2}F_{4}$ (B0mTorr) $+$ CO (150mTorr) $+$ He\\ each gave the same signal to noise ratio, when the reactants were flown through the multiple reflection cell at the total pressure of 1 Torr. We determined the rotational constants, the centrifugal distortion constants and the spin-rotation interaction constants in each vibrational states, both of $F^{12}CO$ and $F^{13}CO$. en_US
dc.format.extent 90738 bytes
dc.format.mimetype image/jpeg
dc.language.iso English en_US
dc.title DIODE LASER SPECTROSCOPY OF THE FCO RADICAL en_US
dc.type article en_US