# INFRARED AND RAMAN SPECTRA OF AMINE ADDUCTS OF TRIMETHYLGALLANE

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 Title: INFRARED AND RAMAN SPECTRA OF AMINE ADDUCTS OF TRIMETHYLGALLANE Creators: Bradley, C. B.; Odom, J. D.; Durig, J. R. Issue Date: 1980 Publisher: Ohio State University Abstract: The infrared spectra of solid ammoniatrimethylgallane-$d_{0}$, and $–d_{3}$ and trimethylaminetrimethylgallane have been recorded from 4000 to $80 cm^{-1}$. The Raman spectra of the solids have been recorded from 3400 to $25 cm^{-1}$ the Raman spectrum of liquid trimethylaminetrimethylgallane was recorded from 3200 to $50 cm^{-1}$ at a temperature of about $50^{\circ} C$. The Ga-N stretch appears at $357 cm^{-1}$ in $NH_{3}Ga(CH_{3})_{3}$ and at $348 cm^{-1}$ in $ND_{3}Ga (CH_{3})_{3}$. A complete vibrational assignment will be presented for these molecules. Description: Author Institution: URI: http://hdl.handle.net/1811/11176 Other Identifiers: 1980-FD-4