# THE FAR ULTRAVIOLET SPECTRUM OF THIOFORMALDEHYDE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/10353

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 Title: THE FAR ULTRAVIOLET SPECTRUM OF THIOFORMALDEHYDE Creators: Judge, R. H.; Moule, D. C.; Drury-Lessard, C. R. Issue Date: 1978 Publisher: Ohio State University Abstract: The electronic absorption spectrum of thioformaldehyde, $H_{2}CS$ $D_{2}CS$, has been recorded from 2200 to 1800 {\AA}. Four electronic transitions have been identified in the spectrum and have been assigned to the $\pi\rightarrow\pi^{*} n\rightarrow 4s, n\rightarrow 4p_{y}$ and $n\rightarrow 4p_{z}$ electron promotions. Both the $\pi\rightarrow\pi^{*}$ and the $n\rightarrow 4s$ transitions exhibit discrete vibrational and rotational structure. An analysis of the high resolution spectra of these two lower systems will be discussed. Description: Author Institution: Department of Chemistry, Brock University; McMaster University, Brock University URI: http://hdl.handle.net/1811/10353 Other Identifiers: 1978-FB-01