MICROWAVE SPECTRA OF HIGHLY VIBRATIONALLY EXCITED FCN AND HCCCN IN GLOW DISCHARGES

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Title: MICROWAVE SPECTRA OF HIGHLY VIBRATIONALLY EXCITED FCN AND HCCCN IN GLOW DISCHARGES
Creators: Saykally, R. J.; Piltch, N. D.; Szanto, P. G.; Woods, R. C.
Issue Date: 1977
Publisher: Ohio State University
Abstract: Rotational transitions of the linear molecules FCN and HCCCN have been detected in excited vibrational states several thousand $cm^{-1}$ above the ground state in DC glow discharges through various gas mixtures. A large number of lines have been found for cyanoacetylene in $N_{2}/CH_{4}$ discharges, corresponding to both stretching and bending modes. Satellites corresponding to all normal modes of FCN have been observed in $N_{2}/CF_{4}$ discharges. Efforts to obtain precise equilibrium structures and anharmonic force fields of these molecules are in progress.
Description: Author Institution: Department of Chemistry, University of Wisconsin
URI: http://hdl.handle.net/1811/10323
Other Identifiers: 1977-WG-11
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