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VIBRATIONAL SPECTRA AND STRUCTURE OF PERFLUOROVINYL-DIFLUOROBORANE AND PERFLUOROVINYLDICHLOROBORANE

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/10114

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Title: VIBRATIONAL SPECTRA AND STRUCTURE OF PERFLUOROVINYL-DIFLUOROBORANE AND PERFLUOROVINYLDICHLOROBORANE
Creators: Kalasinsky, V. F.; Durig, J. R.; Stampf, E. J.; Odom, J. D.
Issue Date: 1977
Abstract: The infrared spectra of gaseous (3000-30 $cm^{-1}$) and solid (3000-200 $cm^{-1}$) perfluorovinyldifluoroborane and perfluorovinyldichloroborane have been recorded along with the Raman spectra (3000-30 $cm^{-1}$) of all three physical states. The vibrational data have been interpreted in detail and are consistent with a planar geometry for both compounds. The question of $\Pi$-delocalization through the C-B bond is discussed.
URI: http://hdl.handle.net/1811/10114
Other Identifiers: 1977-RD-4
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