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NON-SYMMETRIC PUSH-PULL MOLECULES IN THE GAS PHASE: HIGH RESOLUTION STARK SPECTROSCOPY OF $M$-AMINOBENZOIC ACID

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/46140

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dc.creator Fleisher, Adam J. en_US
dc.creator Morgan, Philip J. en_US
dc.creator Pratt, David W. en_US
dc.date.accessioned 2010-07-12T13:59:11Z
dc.date.available 2010-07-12T13:59:11Z
dc.date.issued 2010 en_US
dc.identifier 2010-WF-08 en_US
dc.identifier.uri http://hdl.handle.net/1811/46140
dc.description Work supported by NSF (CHE-0911117). en_US
dc.description Author Institution: Department of Chemistry, University of Pittsburgh, 15260 en_US
dc.description.abstract The permanent electric dipole moments of two conformers of \textit{m}-aminobenzoic acid (MABA) in their ground and electronically excited states have been experimentally determined by Stark-effect measurements in a molecular beam. The two conformers, differing by a rotation about the bond connecting the carboxylic acid group and aniline ring, have very similar rotational constants. However, the two conformers may be unambiguously assigned using their respective permanent dipole moment orientations. The possibility of excited state mixing in this non-symmetric biologically relevant push-pull molecule will be discussed. en_US
dc.language.iso en en_US
dc.title NON-SYMMETRIC PUSH-PULL MOLECULES IN THE GAS PHASE: HIGH RESOLUTION STARK SPECTROSCOPY OF $M$-AMINOBENZOIC ACID en_US
dc.type Article en_US
dc.type Image en_US
dc.type Presentation en_US

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