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THE {A} STATES OF THE C${_3}$-Ar AND C${_3}$-Kr VAN DER WAALS COMPLEXES: FLUORESCENCE POLARIZATION AND SATURATION

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/31125

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Title: THE {A} STATES OF THE C${_3}$-Ar AND C${_3}$-Kr VAN DER WAALS COMPLEXES: FLUORESCENCE POLARIZATION AND SATURATION
Creators: Chen, Kan-Sen; Cheng, Shin-Shin; Chao, Jun-Mei; Merer, A. J.; Hsu, Yen-Chu
Issue Date: 2006
Publisher: Ohio State University
Abstract: The degree of polarization of the laser-induced fluoresence of the \ {A}$-$\ {X} system of the C${_3}$-Ar and C${_3}$-Kr van der Waals complexes was determined and has been used to probe the orientation of the transition dipole of C${_3}$ with respect to the principal axis of each complex. The fluorescence polarization was measured near the 2$^{2-}_0$, 2$^{2+}_0$, 1$^1_0$ and 2$^{1+}_0$3$^1_0$ bands of C${_3}$ under supersonic expansion conditions. The results of polarization measurements of several van der Waals spectral features will be compared with those of the associated R(0) lines of free C${_3}$. The effect of partial saturation on the fluorescence polarization measurements will be discussed.
Description: Author Institution: Institute of Atomic and Molecular Sciences, Academia Sinica, P. O. Box 23-166, Taipei 10617, R. O. C.
URI: http://hdl.handle.net/1811/31125
Other Identifiers: 2006-TF-11
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