OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

VIBRATIONAL ZEKE PHOTOELECTRON SPECTROSCOPY OF CHLOROBENZENE CATION

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/29638

Show full item record

Files Size Format View
1995-RF-07.jpg 42.28Kb JPEG image Thumbnail of VIBRATIONAL ZEKE PHOTOELECTRON SPECTROSCOPY OF CHLOROBENZENE CATION

Title: VIBRATIONAL ZEKE PHOTOELECTRON SPECTROSCOPY OF CHLOROBENZENE CATION
Creators: Panov, Sergey I.; Wright, Timothy G.; Miller, Terry A.
Issue Date: 1995
Publisher: Ohio State University
Abstract: Zero-kinetic-energy (ZEKE) photoelectron spectroscopy was used to probe the vibrational levels in the ground electronic state of the chlorobenzene cation using a two-color photoionization scheme via the $S_{1}$ electronic state of the $neutral^{a}$. Exciting through different $S_{1}$ vibrational levels has revealed mixing of some $S_{1}$ normal coordinates in the ground state of the cation. A previously-identified Fermi resonance in the $S_{1}$ state of the neutral is also confirmed by the ZEKE spectra. The adiabatic ionization energy is measured as $73170 \pm 5 cm^{-1}$.
Description: $^{a}$T. G. Wright, S. I. Panov and T. A. Miller J. Chem. Phys. 102(12), XXXX March 1995.
Author Institution: The Ohio State University, Columbus, OH 43210; The University, Southampton, United Kingdom S09 1NH
URI: http://hdl.handle.net/1811/29638
Other Identifiers: 1995-RF-07
Bookmark and Share