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INTEGRATED INTENSITIES OF OH VIBRATIONAL OVERTONES IN ALCOHOLS

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/19579

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Title: INTEGRATED INTENSITIES OF OH VIBRATIONAL OVERTONES IN ALCOHOLS
Creators: Phillips, J. A.; Orlando, J. J.; Tyndall, G.; Vaida, V.
Issue Date: 1999
Publisher: Ohio State University
Abstract: Intensities for several OH vibrational overtone bands have been measured for vapor phase methanol, ethanol, and isopropanol. The trends in the intensities as a function of excitation level have been modeled by two empirical approaches, yielding intensity predictions for the higher overtone transitions, up to $7\nu(OH)$. These methods were also applied to recent $HNO_{3}$ overtone measurements, resulting in new intensity predictions for higher, photochemically-active overtone bands, which are compared with theoretical estimates.
Description: Author Institution: Department of Chemistry, University of Wisconsin-Eau Claire; Atmospheric Chemistry Division, National Center for Atmospheric Research; Department of Chemistry and Biochemistry, University of Colorado
URI: http://hdl.handle.net/1811/19579
Other Identifiers: 1999-WH-13
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