OSU Navigation Bar

The Ohio State University University Libraries Knowledge Bank

$^{14}N$ HYPERFINE SPLITTINGS IN THE MICROWAVE SPECTRUM OF FOUR ISOTOPOMERS OF $N_{2}O-HCl$

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/19368

Show full item record

Files Size Format View
1999-RG-06.jpg 78.80Kb JPEG image Thumbnail of $^{14}N$ HYPERFINE SPLITTINGS IN THE MICROWAVE SPECTRUM OF FOUR ISOTOPOMERS OF $N_{2}O-HCl$

Title: $^{14}N$ HYPERFINE SPLITTINGS IN THE MICROWAVE SPECTRUM OF FOUR ISOTOPOMERS OF $N_{2}O-HCl$
Creators: Leung, Helen O.
Issue Date: 1999
Publisher: Ohio State University
Abstract: In the previously reported microwave spectrum of $N_{2}O-HCl^{a}$, the hyperfine splittings due to the quadrupolar $^{14}N$ nucleus were not resolved. The spectra of all three of the HCl-containing isotopomers from the previous study $(^{14}N_{2}O-H^{35}Cl,{^{14}}N_{2}O-H^{37}Cl,{^{15}}N{^{14}}NO-H^{35}Cl)$ plus that of the additional isotopomer $^{15}N^{14}NO-H^{37} Cl$ have been recorded under higher resolution that permits the full analysis of the nuclear electric quadrupole hyperfine structure for both chlorine and nitrogen. These data provide additional information regarding the angular properties of the complex as well as giving insight into the nature of electric field gradient perturbations accompanying complex formation.
Description: $^{a}$ D.J. Pauley. M.A. Roehrig, L. Adamowicz, J.C. Shea, S.T. Haubrich, and S.G. Kukolich, J. Chem. Phys. 94, 899 (1991).
Author Institution: Department of Chemistry, Mount Holyoke College
URI: http://hdl.handle.net/1811/19368
Other Identifiers: 1999-RG-06
Bookmark and Share