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The $\bar{A}-\bar{X}$ Systems of the Alkyl-O and Alkyl-S Radicals

Please use this identifier to cite or link to this item: http://hdl.handle.net/1811/17139

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Title: The $\bar{A}-\bar{X}$ Systems of the Alkyl-O and Alkyl-S Radicals
Creators: Damo, Cristino P.; Foster, Stephen C.; Hsu, Yen-Chu; Liu, Xianming; Kung, Chung-Yi; Miller, Terry A.
Issue Date: 1986
Publisher: Ohio State University
Abstract: Rotationally cold spectra $(<5K)$ of the $\bar{A}-\bar{X}$ systems of $CH_{3}O, C_{2}H_{6}O. iC_{3}H_{7}O$ and $CH_{3}S$ have been observed by LIF. These radicals were produced by UV laser photolysis of a suitable precursor seeded in a rare-gas free-jet expansion. The ``hot'' fragments are rapidly cooled by collisions in the expansion and are subsequently probed with a Nd:YAG-pumped dyelaser system. Details of this experimental technique will be presented and the analysis of the $CH_{3}S$ data will be discussed.
Description: Address: Department of Chemistry. The Ohio State University, Columbus, OH. 43210
Author Institution:
URI: http://hdl.handle.net/1811/17139
Other Identifiers: 1986-WG-4
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