MOLECULAR G-VALUES, MAGNETIC SUSCEPTIBILITIES, AND MOLECULAR QUADRUPOLE MOMENTS IN CYCLOPROPENE, FLUOROBENZENE, FURAN, THIOPHENE, TRIMETHYLENE OXIDE, TRIMETHYLENE SULFIDE, ETHYLENE OXIDE, AND ETHYLENE SULFIDE.

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1969

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Ohio State University

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The molecular Zeeman effect has been observed in the series of ring compounds listed above. Both the first order (H) and second order ($H^{2}$) Zeeman parameters are recorded and listed for the above molecules. The first-order parameters are the molecular magnetic moments or molecular g-values and the second-order parameters are the magnetic susceptibility anisotropies. Combining these experimental parameters gives the molecular quadrupole moments for these molecules. The electronic distributions are discussed as well as the magnetic properties of the rings. The sign of the electric dipole moment of cyclopropene is also obtained.

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Author Institution: Noyes Chemical Laboratory, University of Illinois

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